One may think of microwaves in the oven as light shining through
translucent food, with the light that gets absorbed being turned into
heat. This is a good description of what happens when the food is a
continuous mass measuring more than about 6 centimetres in all
directions.
However, if the food mass is smaller
and oddly shaped, the interaction between the wavelength of the
radiation (usually around 12.24 centimetres) and the shape becomes
dominant. Microwaves then behave more like radio waves, and some
slender, spiky or complex-shaped vegetables become electrical
conductors. These conductors act like radio aerials along which
electric charges surge back and forth, typically at about 2.5 billion
times a second. Wherever these "aerials" form small gaps or fine
contacts, electrons leap across, creating hot spots or sparks that
scorch the food. This is why conductors such as forks, plates decorated
with metal leaf, or unsuitably shaped foods cause arcing.
If
your broccoli is in firm contact with the lumps of sweet potato or
thoroughly wet, the fluid clogs the gaps and masks any fine tips,
preventing harm, but wherever the electrons can arc across fine
contacts or gaps, you get sparks or charring.
Jon Richfield, Somerset West, South Africa