Most chemical components of dank smells are products of microbial
activity, and microbial activity requires water. Once the chemicals are
present they can reach the nose only by escaping into the air.Most
are fatty acids, amino compounds and the like, with charged chemical
groups that readily bind to non-volatile molecules such as large
proteins and carbohydrates. Once they have latched onto, say, dry cloth
or leather, they cannot float freely into the air so there is not much
to smell. However, these charged groups have an affinity for polar
molecules, and the most polar of common molecules is water. So when the
object gets wet, water molecules prise loose the odour molecules,
cocooning them in tiny mobile parcels of water. For good or ill many
escape into the air, reaching nearby noses in vast numbers.Accordingly,
a powerful deodorising strategy is to release other molecules that
immobilise pong molecules by binding them with complementary charged
groups. Chlorophyll combats smells partly by presenting a metal atom
that binds the active groups of many smell molecules. Similarly, by
binding key molecules, partly oxidised paraffin wax vapour from the
smoke of burning candles also helps clear a room of the stench of
cigarettes.Jon Richfield, Somerset West, South Africa