Humans don't exhale CO2 because they "only use so much", we exhale CO2 because for the most part it is toxic to us.
Knowing the amount of CO2 exhaled by humans would not provide a good indicator of how much CO2 is absorbed by plants.
All plants vary in absorption rates of nutrients. Aside from directly measuring the amount of CO2 present in an environment before and after the introduction of a plant, I can't think of a reasonable way to deduce their consumption from the amount which humans exhale.