You know, the definition of temperature gecomes very tricky when you are speaking of single molecules or atoms. Temperature is a mass quality, referring to averages of the relative motions of molecules in a gas or substance.
Referring to "temperature" of a single atom becomes much like referring to the kinetic energy of a body. There are other aspects too, such as the excitation of its electrons, but in such matters one has to be very careful of how you define what exactly you are talking about if you want to be sure of talking sense.
Just as a PS, some of the "vibration" involved is of the nucleus and the orbital electrons relative to each other. Incidentaly, at really, really far cryogenic temperatures the two are not well coupled, and this makes it difficult to get close to absolute zero, because you cannot do much to cool the nucleus by cooling the electrons beyond a certain degree, for example.