I don't know. For one thing, in my presence ripe blackberries don't last.
The only thing that springs to (my) mind is that it sounds like the setting of pectins in the juice. Green blackberries contain the most pectin, but the molecules are too tightly bound to use without special preparation. Part of the ripening process however, is to separate many such molecules from the cell walls, partly under enzymatic control, so the fragments of cell wall that escaped with the juice separate out nicely and settle into a weak gel.
Which is all you need for a junket.
So that is my bet.